Submarine in the ocean. Text reads: "Geoscience Today: Researchers Studying Ocean Transform Faults, Describe a Previously Unknown Part of the Geological Carbon Cycle"

Researchers Studying Ocean Transform Faults, Describe a Previously Unknown Part of the Geological Carbon Cycle

Chief Scientist Frieder Klein and Deep Rover Pilot Alan Scot exploring a submerged carbonate platform. (Photo by: Novus Select) Woods Hole, Mass. Republished with permission. Original article here. Studying a rock is like reading a book. The rock has a story to tell, says Frieder Klein, an associate scientist in the Marine Chemistry & Geochemistry Department at the Woods Hole Oceanographic Institution (WHOI). The rocks that Klein and his colleagues analyzed from the submerged flanks of the St. Peter and St. Paul Archipelago in the St. Paul’s oceanic transform fault, about 500 km off the coast of Brazil, tells a fascinating and previously unknown story about parts of the geological carbon cycle. Transform faults, where tectonic plates move past each other, are one of three main plate boundaries on Earth and about 48,000 km in length globally, with the others being the global mid-ocean ridge system (about 65,000 km) and subduction zones (about 55,000 km). Carbon cycling at mid-ocean ridges and subduction zones has been studied for decades. In contrast, scientists have paid relatively scant attention to CO2 in oceanic transform faults. The transform faults were considered “somewhat boring” places for quite some time because of the low magmatic activity there, says Klein. “What we have now pieced together is that the mantle rocks that are exposed along these ocean transform faults represent a potentially vast sink for CO2,” he says. Partial melting of the mantle releases CO2 that becomes entrained in hydrothermal fluid, reacts with the mantle closer to the seafloor, and is captured there. This is a part of the geological carbon cycle that was not known before,” says Klein, lead author of a new journal study “Mineral Carbonation of Peridotite Fueled by Magmatic Degassing and Melt Impregnation in an Oceanic Transform Fault,” published in the Proceedings of the National Academy of Sciences (PNAS). Because transform faults have not been accounted for in previous estimates of global geological CO2 fluxes, the mass transfer of magmatic CO2 to the altered oceanic mantle and seawater may be larger than previously thought.” ”The amount of CO2 emitted at the transform faults is negligible compared to the amount of anthropogenic – or human driven – CO2,” says Klein. “However, on geological timescales and before humans emitted so much CO2, geological emissions from Earth’s mantle – including from transform faults – were a major driving force of Earth’s climate.” As the paper states, “global anthropogenic CO2 emissions are estimated to be on the order of 36 gigatons (Gt) per year, dwarfing estimates of average geological emissions (0.26 Gt per year) to the atmosphere and hydrosphere. Yet, over geological timescales, emissions of CO2 sourced from Earth’s mantle have been pivotal in regulating Earth’s climate and habitability, as well as the C [carbon]-concentration in surface reservoirs, including the oceans, atmosphere, and lithosphere.” Klein adds that “this is before anthropogenic combustion of fossil fuels, of course” “In order to fully understand modern human-caused climate change, we need to understand natural climate fluctuations in Earth’s deep past, which are tied to perturbations in Earth’s natural carbon cycle. Our work provides insights into long-timescale fluxes of carbon between Earth’s mantle and the ocean/atmosphere system,” says co-author Tim Schroeder, member of the faculty at Bennington College, Vermont. “Large changes in such carbon fluxes over millions of years have caused Earth’s climate to be much warmer or colder than it is today.” To better understand carbon cycling between Earth’s mantle and the ocean, Klein, Schroeder, and colleagues studied the formation of soapstone “and other magnesite-bearing assemblages during mineral carbonation of mantle peridotite” in the St. Paul’s transform fault, the paper notes. “Fueled by magmatism in or below the root zone of the transform fault and subsequent degassing, the fault constitutes a conduit for CO2-rich hydrothermal fluids, while carbonation of peridotite represents a potentially vast sink for the emitted CO2.” The researchers argue in the paper that “the combination of low extents of melting, which generates melts enriched in incompatible elements, volatiles and particularly CO2, and the presence of peridotite at oceanic transform faults creates conditions conducive to extensive mineral carbonation.” The rocks were collected using human-occupied vehicles during a 2017 cruise to the area. Finding and analyzing these rocks “was a dream come true. We had predicted the presence of carbonate-altered oceanic mantle rocks 12 years ago, but we couldn’t find them anywhere,” says Klein. “We went to the archipelago to explore for low-temperature hydrothermal activity, and we failed miserably in finding any such activity there. It was unbelievable that we were able to find these rocks in a transform fault, because we found them basically by chance while looking for something else.” Funding for this research was provided by the Dalio Ocean Initiative, the Independent Research & Development Program at WHOI, and the National Science Foundation. Authors: Frieder Klein*, Timothy Schroeder, Cédric M. John, Simon Davis3, Susan E. Humphris1, Jeffrey S. Seewald1, Susanna Sichel, Wolfgang Bach, and Daniele Brunelli,1 Affiliations: *Corresponding author About Woods Hole Oceanographic Institution: The Woods Hole Oceanographic Institution (WHOI) is a private, non-profit organization on Cape Cod, Massachusetts, dedicated to marine research, engineering, and higher education. Established in 1930, its primary mission is to understand the ocean and its interaction with the Earth as a whole, and to communicate an understanding of the ocean’s role in the changing global environment. WHOI’s pioneering discoveries stem from an ideal combination of science and engineering—one that has made it one of the most trusted and technically advanced leaders in basic and applied ocean research and exploration anywhere. WHOI is known for its multidisciplinary approach, superior ship operations, and unparalleled deep-sea robotics capabilities. We play a leading role in ocean observation and operate the most extensive suite of data-gathering platforms in the world. Top scientists, engineers, and students collaborate on more than 800 concurrent projects worldwide—both above and below the waves—pushing the boundaries of knowledge and possibility. For more information, please visit www.whoi.edu

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The Niagara Escarpment in the distance at sunset. The cliff is surrounded by autumn coloured trees. On top of the photo text reads: "Geoscience Today. The Niagara Escarpment is crumbling- here's how, and why you should care."

The Niagara Escarpment is Crumbling—Here’s How, and Why You Should Care

If you visit or live near a geological landform, such as an escarpment, waterfall, or hillslope, you may notice that rock debris accumulates over time. Patrons of the Niagara Escarpment’s Bruce Trail, for instance, can observe rock blocks ranging from the size of a cell phone to a small car. To a hiker, fallen rock may not seem concerning. Yet what happens when geology meets urban infrastructure? The Niagara Escarpment is a large sedimentary landform which spans 400km across the northeastern United States and southern Ontario. Composed of dolostones, limestones, sandstones, and shales from the Paleozoic Era, its face is steep and heavily fractured. Each stratum, or layer, of rock has a unique composition which dictates its susceptibility to erosion. For instance, thick, resistant layers of the Irondequoit dolostone are often undercut by the softer Rochester shale which erode at a faster rate. This produces sharp overhangs which create angular blocks when there is not enough rock to support the overlying material. The escarpment bisects a number of urban areas, such as Hamilton, Ontario, where it is integrated into city infrastructure. This poses significant risks because the fractured escarpment face experiences frequent rockfalls which threaten the safety of citizens and have caused considerable infrastructure damage. For many years, the reason for the rapid weathering rates observed on the escarpment was unknown. New research has revealed the role of temperature changes in the development of fractures. How is the Escarpment Weathered? There are a variety of processes responsible for the weathering of rock, such as be chemical, mechanical (e.g., cracking), fluvial (e.g., flowing water), or biological (e.g., tree roots) in nature. However, the escarpment’s location in a temperate climate is unique because it is subject to cold winters and warm summers. This means that temperature plays a significant role in freeing rock from the escarpment face. Freeze-thaw weathering describes processes which create fractures in rock by causing water contained within pores or pre-existing cracks to freeze and thaw over time. When water freezes, it expands. This forces apart a body of rock from the interior, often producing stresses which exceed the strength of the rock. Freeze-thaw processes can occur within individual pores saturated with water, or on larger scales where ice lenses accumulate in pre-existing cracks. During the winter months, this form of weathering produces debris ranging from small flakes to large angular blocks.  Thermal weathering is similar to freeze-thaw in that it involves fluctuations between warmer and cooler temperatures. Rock expands during warming and contracts during cooling, which causes the rock to deform throughout the day.  Over time, these temperature cycles can create enough stress to cause fractures to develop. This is referred to as thermal fatigue, because each fluctuation is not individually powerful enough to fracture the rock, but over time the stresses accumulate. Conversely, thermal shock describes events of rapid temperature change (which can range from 1°C to over 10°C per minute) that induce high stresses as the rock expands or cools. This can cause instantaneous cracking.  These weathering processes are not limited to geological landforms. Sidewalks, buildings, and even prehistoric rock art are all susceptible to temperature changes.  How is Weathering Studied? At McMaster University, our research group studies these processes from a variety of perspectives. My work implements a network of remote temperature probes installed at exposed rock outcrops across the escarpment. At each site, probes are inserted into pre-existing fractures and affixed to the rock surface to measure temperature at one-minute intervals. This reveals changes on short time scales which enables us to identify thermal shock events and freeze-thaw cycles. By collecting data year-round, the temperature probes also provide information about the seasonality of fracturing.  To assess the spatial distribution of weathering, an infrared thermal camera is employed which photographs differences in surface temperature across rock outcrops. Our group uses a rock trap (pictured below), to collect samples of falling rock generated by weathering processes. This is paired with drone-based 3D models which enable us to identify the rate of weathering and location in which blocks have fallen from the escarpment face.  My research also involves climate modelling to predict future changes in weathering intensity using a suite of regional climate models.  Climate Change Our research suggests that climate change may exacerbate weathering processes by increasing the range of temperatures experienced by rock throughout the day. In exposed rock faces, the surface warms rapidly in comparison to pre-existing fractures which are insulated from atmospheric conditions. This creates a thermal gradient between the fracture and rock surface—during the day, the surface is warmer than fractures, whereas at night the fractures are insulated from cooling and remain at higher temperatures than the surface.  As the climate warms, this effect will be exacerbated. Repeated warming and cooling will increase the gradient of temperature between the surface and fractures, promoting processes such as freeze-thaw and thermal weathering which are predicated on thermal cyclicity.  Shifts in the amount of precipitation may also play a role. In areas where climate change will bring increased rain and snowfall, moisture conditions will raise the likelihood for freeze-thaw expansion in rock. This further raises the likelihood for fractures to grow. Why Should I Care? The Niagara Escarpment is well integrated into urban infrastructure. Rapid rates of weathering and the location of exposed rock walls poses significant safety risks to commuters and pedestrians alike.  The portion of the escarpment which passes through the city of Hamilton, Ontario is a pertinent example. Between 2007 and 2017, there were nearly 40 damage claims from falling rocks, and eight major rock falls over a two-year span each incurring $25,000–$500,000 in costs. While the city spends $300,000 annually to update preventative erosion measures, research suggests that numerous areas remain susceptible to rockfall and require $12 million in protective measures. Commuters along the Niagara Escarpment routinely experience rock hazards, such as a 2016 event in which a truck-sized boulder nearly struck cars along the 403 Highway.  These issues are not unique to the Niagara Escarpment alone—geological landforms in all temperate environments

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